Henry Nicholls was out one ball after Taylor, both falling to the young leg-spinner Shadab Khan, and Tom Latham (35) and Mitchell Santner (6) fell to consecutive deliveries from Rumman Raees and Hasan Ali.
Williamson and Taylor kept Pakistan on the back foot as they forged a 74-run stand, during which Williamson surpassed his fifty.
After 10 overs, the tourists were three down for just nine runs and while they struggled to stay afloat, Babar Azam was unnecessarily run out.
Hasan then departed as he was the victim of a superb catch by Williamson at midwicket.
But Munro was out for 8 in the second over, slashing across the line at a ball from Faheem Ashraf and delivering a skied catch to Pakistan wicketkeeper and captain Sarfraz Ahmed.
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It was Pakistan's lowest total against New Zealand and the hosts' winning margin eclipsed the previous best of 138 runs when the two sides met at Christchurch in 2001. Ferguson and Munro took care of the rest by taking 2 wickets each.
"It was very disappointing, a tough loss", said the skipper during post-match ceremony, after staying not out at 14 as the rest of the wickets crumbled around him. We will sit together and sort it out. "The problem is (facing) the new ball", he lamented.
The first in Wellington a week ago was by 61 runs, while the second on Wednesday in Nelson was by eight wickets.
He says they're "built strongly as a team, and have come a long way". The answer awaits just a few hours to surface as the two Teams are now again set to meet at University Oval in Dunedin on Saturday. It was going to be hard to score. Focus is to win each game.
Boult was awarded man of the match honours, finishing the innings with 5/17 off 7.2 overs. "Collective effort. Wanted to get the series done, knew we had to fight hard with only 250 on the board".